My greatest electrical shock came from a vintage 1953 Emerson color TV with a metal picture tube. I was working my first "paid" job at a local TV repair shop. As a Senior in high school, I was wearing my brand new class ring. I should have known better. The boss was out making a service call and I was alone, trying to restore life to this twelve year old TV. In a Eureka moment, I found and replaced the offending components, and the set was now making a color picture!
I'd just set the high voltage to the proper 25,000 volts and went about my business of making some last minute tweaks to the set before shutting it down and putting the chassis back in the cabinet. My hand was about four inches from the heavily insulated CRT shroud when I saw a huge spark jump to my class ring. That is the last thing I remember. When I came to, I was outdoors in the rear parking lot of the shop in my shirt sleeves. It was winter, and it was lightly snowing. I have no idea how I got there. When I got myself back inside the building, I discovered that almost 30 minutes had elapsed. The TV had died from arcing through the hole in the insulation where I got the shock. There was a giant black pitted area on the side of my ring where the arc had hit, and my finger was burned where it came in contact with the ring. I think that was the last day I ever wore it...
From that experience, I learned to never wear any kind of jewelry when working with electricity. Even 12 volts in your car can be very uncomfortable when it heats up your ring to a couple of hundred degrees by becoming a conductor to ground.